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Via surface plasmon resonance (SPR) of Bi and La3+ doping techniques, a series of La3+-doped BiOCl microspheres which contained in situ deposited Bi nanoparticles were synthesized by a facile one-step solvothermal pathway. The introduction of semimetal Bi could obviously narrow the band gap (Eg) of BiOCl from 3.33 to 2.91 eV, along with the creation of oxygen vacancies (OVs) on the surface of BiOCl...
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