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A new rhombus-shaped tetranuclear dysprosium cluster, [Dy4(μ3-OH)2L6(tmhd)4]·CH2Cl2·8CH3CN (1) (HL=5-(4-fluorobenzylidene)-8-hydroxylquinoline; tmhd=2,2,6,6-tetramethyl-3,5-heptanedione), has been synthesized and completely characterized. The X-ray structural analysis exhibit that compound 1 contains one Dy4 center with rhombus-shaped arrangement, and each Dy(III) ion of 1 is located in a distorted...
Three new dinuclear lanthanide compounds, [Ln(hfac)2L]2 (Ln(III)=Gd (1), Tb (2) and Er (3), hfac=hexafluoroacetylacetonate and HL=2-[(4-ethylphenyl)imino]methyl-8-hydroxyquinoline), have been synthesized and characterized by elemental analysis, IR, PXRD and single crystal X-ray diffraction. The X-ray structural analysis exhibit that 1–3 are phenoxo-O-bridged dinuclear complexes and central Ln(III)...
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