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In ihrer Zuschrift auf S. 9016 ff. beschreiben K. Sugiyasu, M. Takeuchi et al. die Mikrophasentrennung in Polythiophen‐Copolymeren mit nichtfunktionalisierten und abgeschirmten Blöcken. π‐π‐Stapelung der nichtfunktionalisierten Blöcke führt zu einem Ensemble gestapelter und isolierter Polythiophene.
All‐polythiophene diblock copolymers, comprising one unsheathed block and one fenced block, were synthesized through catalyst‐transfer polycondensation. The unsheathed block self‐assembles through π‐π stacking, thereby inducing microphase separation. Consequently, we have succeeded in creating a microphase separation comprising an ensemble of stacked and isolated polythiophenes. This achievement could...
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