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A new method has been developed for the Pd-catalyzed direct carbonylation of indoles with phenylacetylenes. The process involved the initial iodination of the indole to afford the corresponding 3-iodo-indole, which was subsequently carbonylated with a variety of different alkynes using Pd(0) to yield the indole-3-alkynones. In contrast to the traditional Pd-catalyzed oxidative carbonylation strategy,...
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