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Monoterpenes such as α-pinene, β-pinene, limonene and isolimonene undergo smooth hydroalkoxylation in the presence of 20mol% of FeCl 3 under mild reaction conditions to produce a wide range of the corresponding ethers in excellent yields and with high selectivity.
Alkyl azides were prepared in good yields by treatment of allylic and benzylic alcohols with a molar equivalent of NaN 3 in the presence of BF 3 .Et 2 O in dioxane.
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