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The low energy sidebands of an emission spectrum contain information about the difference between the ground and the excited state molecular structures. The structural information that can be extracted from the sideband intensities and structure decreases as the component bandwidths increase, but there is significant structural information in the sidebands of the charge transfer emission spectra of...
The absorption spectra and emission spectral band shapes of several polypyridine-ligand (PP) bridged bis-ruthenium(II) complexes imply that the Ru(II)/Ru(III) electronic coupling is weak in their lowest energy metal to ligand charge transfer (MLCT) excited states. Many of these PP-bridging ligands contain pyrazine moieties and the weak electronic coupling of the excited states contrasts to the strong...
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