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Electrochemical reactions (oxidation or reduction) start when the electronic levels of the redoxsystem within the electrolyte cross the Fermi level EF of the electrode - from below to above EF in the case of the oxidation and from above to below in the case of reduction. This energetic shift of the redox level is effected by changing the electrochemical potential of the electrode. Hot electrons above...
Electrochemical reactions (oxidation or reduction) start when the electronic levels of the redoxsystem within the electrolyte cross the Fermi level EF of the electrode - from below to above EF in the case of the oxidation and from above to below in the case of reduction. This energetic shift of the redox level is effected by changing the electrochemical potential of the electrode. Hot electrons above...
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