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The accelerating effect of terminal n‐alkyl groups (TAGs) on the non‐isothermal crystallization of poly(L‐lactide)/poly(D‐lactide) blends increased with TAG length in the low temperature range below 100 °C and that on isothermal stereocomplex crystallization of poly(L‐lactide)/poly(D‐lactide) blends became maximal at terminal n‐hexyl group in the high temperature range above 165 °C. However, the decelerating...
Poly(l-lactide) (PLLA) polymers having terminal n-alkyl groups with a wide variety of lengths (C 0 –C 22 ) were synthesized by ring-opening polymerization of l-lactide in the presence of coinitiators of l-lactic acid (C 0 ), 1-hexanol (C 6 ), 1-dodecanol (C 12 ), and 1-docosanol (C 22 ) and their segmental mobility and non-isothermal and isothermal crystallization...
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