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The reaction of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dmpe)(PEt3)2 (dmpe=Me2PCH2CH2PMe2) in the ratio of 1:1 yields the complex {1,2-C6H4(SiMe2)(SiH2)}PtII(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis)silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane...
Treatment of 1,2-C6H4(SiH3)(SiH3) (1) with [Pt(depe)(PEt3)2] (depe=Et2PCH2CH2PEt2) in the ratio of 1:1 yields the complex [PtII{1,2-C6H4(SiH2)(SiH2)}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand...
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