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The cyclocopolymerization of 1,6-heptadiene (HPD) with ethylene (E) by a series of half-sandwich scandium alkyl catalysts bearing various auxiliary ligands have been examined. Significant ligand influence on the copolymerization activity and selectivity was observed. In combination with one equivalent of [Ph3C][B(C6F5)4], the half-sandwich scandium dialkyl complexes bearing a Lewis base THF (1) or...
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