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Composite catalysts for photocatalytic hydrogen (H2) evolution were prepared by loading an organic electron donor–acceptor linked dyad [2-phenyl-4-(1-naphthyl)quinolinium ion, QuPh+–NA] as an organic photosensitizer and Pt or Cu particles as H2-evolution catalysts on alumina-silica. The composite catalysts loading Pt particles were prepared by two different methods; first, Pt particles were deposited...
Formation of 1,2-dioxetane of tetraphenylethylene (TPE) occurs via formation of the electron transfer state of 9-mesityl-10-methylacridinium ion (Acr + -Mes) under visible light irradiation, followed by electron transfer from TPE to the Mes + moiety together with electron transfer from the Acr moiety to O 2 , and the subsequent radical coupling between TPE + and O ...
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