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Chemoselective aerobic oxidation of primary alcohols in the presence of activated secondary alcohols was effected under irradiation of visible light by using (nitrosyl)Ru(salen) complex 6 that possesses bulky 1-ethyl-1-methylpropyl groups at C3, C3′, C5 and C5′, as catalyst. For example, oxidation of n-decanol was >50 times faster than oxidation of 1-phenylethanol at 10°C.
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