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The mechanism of oxidative carbonylation of methanol to dimethyl carbonate (DMC) over Cuβ catalyst was investigated by using in situ DRIFTS; the adsorption of single methanol, carbon monoxide and DMC as well as their mixtures on the Cuβ catalyst were considered. The results indicated that methoxide species are formed when methanol is adsorbed on the catalyst due to presence of CuO x . Only...
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