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The sodium‐rich antiperovskites (NaRAPs) with composition Na3OB (B=Br, Cl, I, BH4, etc.) are a family of materials that has recently attracted great interest for application as solid electrolytes in sodium metal batteries. Non‐Arrhenius ionic conductivities have been reported for these materials, the origin of which is poorly understood. In this work, we combined temperature‐resolved bulk and local...
The sodium‐rich antiperovskites (NaRAPs) with composition Na3OB (B=Br, Cl, I, BH4, etc.) are a family of materials that has recently attracted great interest for application as solid electrolytes in sodium metal batteries. Non‐Arrhenius ionic conductivities have been reported for these materials, the origin of which is poorly understood. In this work, we combined temperature‐resolved bulk and local...
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