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Metal 31-hydroxy-131-oxo-chlorins were systematically prepared and their visible and circular dichroism spectra were measured in a solution. All the synthetic complexes were monomeric in tetrahydrofuran. The Ni/Cu/Pd/Ag(II) complexes were still monomeric after dilution with 99-fold hexane. In contrast, the Co(II) complex, as well as the Mg/Zn/Cd(II) complexes, self-aggregated in 1% (v/v) tetrahydrofuran-hexane...
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