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Influences of nitrogen on the passivity of Fe–20Cr–(0, 1.1)N alloys were examined by in situ electrochemical techniques. Nitrogen was incorporated in the form of (Fe, Cr)-nitrides in the passive film, and Cr was enriched in the film of the alloy with nitrogen. Photocurrent analysis demonstrated that the structure of passive film formed on Fe–20Cr–1.1N alloy is Cr-substituted γ-Fe 2 O 3...
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