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Natural rubber grafted with poly(butyl acrylate) (NR‐g‐PBA) in an attempt to toughen polylactide (PLA) was prepared by grafting butyl acrylate onto natural rubber (NR) through emulsion polymerization. The purified NR‐g‐PBA was confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. NR‐g‐PBA/PLA blend and NR/PLA blend were prepared with a Haake internal melt...
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