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Additional disorder induced by adsorption processes by the molecule of ambient are responsible for deep modulation of conductivity. Observations confirmed the dominated role of the increase of the free carrier concentration due to the increse the shallow trap concentration, for modulation of the conductivity.
Injection of carriers into thin layers of acenes due to adsorption of ethanol activator molecules is considered as a electron transfer reaction between two phases. Complexity of the processes may be diminished with applying electron transfer theory in the meaning of Marcus.
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