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Three double perovskite crystals Rb2MF6 (M = Si, Ni, Pd) are studied using the first‐principles methods. Their structural, electronic, elastic, and thermodynamic properties are calculated; effects of external hydrostatic pressure in the range from 0 to 10 GPa are analyzed. A remarkable feature of all studied compounds is the complicated structure of the valence bands, which consist of several sub‐bands...
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