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The electronic structure of magnetocaloric compound Mn1.1Fe0.9P0.55As0.45, prepared via solid-state sintering was studied. Adiabatic temperature change of 3.6 K was observed through the phase transition found at 273 K. The X-ray diffraction and time-of-flight secondary ion mass spectroscopy were applied to verify the purity and homogeneity of the sample. The X-ray photoemission spectroscopy was used...
The magnetocaloric effect in the MnFeP0.35As0.65−xSix intermetallic compounds, prepared via solid-state sintering was studied. Adiabatic temperature and magnetic entropy changes were obtained in order to characterize these compounds. The substitution of silicon for arsenic leads to a significant enhancement of the magnetocaloric effect for silicon amount x = 0.11. The adiabatic temperature change...
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