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The adhesion force between a silicon nitride tip and a 1-dodecanethiol monolayer have been measured at different loading rates and different humidity. A way to extract the kinetic and interaction potential parameters for a single molecule interaction is demonstrated. The effect of the increase of van der Waals interaction strength per molecule with increasing humidity is explained by assuming a gradual...
Using a modified atomic force microscope, the nanoadhesion between a silicon tip and a monolayer of 1H, 1H, 2H, 2H-perfluorodecyl trichlorosilane was measured at different loading rates. The adhesion force versus loading rate curve could be fitted with two logarithmic terms. The application of a model of thermally activated escape from a bound state to the analysis of the curves made it possible to...
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