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A thermodynamic model has been developed that provides a quantitative description for a wide area of the Mg–Al–Ca system. All available experimental data plus new key experiments using differential scanning calorimetry/differential thermal analysis have been considered to create a dataset which reproduces the primary crystallizing phases, the extensive ternary solubilities of binary phases and the...
Determining whether a four-phase equilibrium in the Mg-rich corner of the Mg–Al–Ca system is a type I (eutectic: L→α(Mg)+C14–Mg 2 Ca+C36–(Mg, Al) 2 Ca) or type II invariant (L+C14–Mg 2 Ca→α(Mg)+C36–(Mg, Al) 2 Ca) has been rather challenging. One recent experimental study proposed a type I eutectic invariant without a micrograph confirming the ternary eutectic. But another...
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