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Multimode Jahn–Teller (JT) and pseudo-Jahn–Teller (PJT) coupling effects in the photoelectron spectrum of ethane are theoretically investigated. In this article, we focus on the vibronic structure of the second excited B∼2Eu electronic manifold of the ethane radical cation which reveals an asymmetric band in the 14.5–16.5eV ionization energy range in the experimental recordings. Ionization of an electron...
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