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Advancing the understanding of lithum nickelate complexes, here we report a family of homoleptic organonickelate complexes obtained by reacting Ni(COD)2 and lithium aryl‐acetylides in the presence of the bidentate donor TMEDA. These compounds represent rare examples of low‐valent transition‐metals supported solely by organolithium ligands. Whilst the solid‐state structures indicate a hexagonal planar...
Advancing the understanding of lithum nickelate complexes, here we report a family of homoleptic organonickelate complexes obtained by reacting Ni(COD)2 and lithium aryl‐acetylides in the presence of the bidentate donor TMEDA. These compounds represent rare examples of low‐valent transition‐metals supported solely by organolithium ligands. Whilst the solid‐state structures indicate a hexagonal planar...
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