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Imidazoles fused with a cyclic system in 1,5‐position were synthesized via the van Leusen imidazole synthesis employing saturated aliphatic tricycles including an imine function in the base catalyzed cycloaddition reaction with p‐toluenesulfonyl‐methyl isocyanide (TosMIC). Thereby, N‐(tosylmethyl)formamide, a decomposition product of TosMIC, was found to act as a promoter of this reaction leading...
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