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The adsorption of ethylene and ethylene oxide has been studied on clean and oxygen-covered Ag(111) using temperature-programmed desorption and reflection-absorption infrared spectroscopy (RAIRS). Ethylene adsorbs weakly on Ag(111) at 80 K with the molecular plane oriented parallel to the surface. The effect of adsorbed oxygen (Θ(O)~0.1) is to increase the heat of adsorption slightly and to cause the...
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