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A new bipyridine fused rhodamine‐like chelating ligand and the corresponding transition metal complexes of platinum(II) and iridium(III) have been designed, synthesized and structurally characterized by X‐ray crystallography. Their photophysical properties and acid‐ or metal ion‐promoted spirocarbon ring‐opening properties have been investigated. The platinum(II) and iridium(III) complexes show a...
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