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Anthracene–pentiptycene hybrid systems 1‐Cn, where n refers to the number of carbon atoms in the linear alkyl chain, crystallize in three different polymorphs, denoted Y (yellow), G (green), and B (blue) forms in terms of the fluorescence color. While all Y‐form crystals show the same yellow‐to‐blue fluorescence color response to the photomechanical stress generated by the anthracene [4+4] photodimerization...
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