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The synthesis of a zinc(II) porphyrin 1 with four appended triazolyl–pyridine chelates is reported. Complexation of the porphyrin peripheral ligands with AgI ions in a 1:2 binding stoichiometry afforded quantitatively the coordination cage [Ag4(1)2]4+. The assembly and disassembly processes of the cage were investigated in solution using UV/Vis spectroscopy. The mathematical analysis of the data obtained...
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