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The influence of tacticity on (1) the conformation of adsorption at a polymer/substrate interface and (2) the magnitude and density of acid-base interactions developed at the interface, has been studied. Films of poly(methyl methacrylate) (PMMA) homopolymers of various tacticities were spin-coated on aluminium mirror substrates. Ellipsometric measurements show that the PMMA film thickness increases...
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