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The influence of hydrophobic interaction between poly[(R)-3-hydroxybutyrate] blocks on block-selected inclusion complexation between amphiphilic poly(ethylene oxide)-poly[(R)-3-hydroxybutyrate]-poly(ethylene oxide)) (PEO-PHB-PEO) triblock copolymers and α-cyclodextrin (α-CD) or γ-cyclodextrin (γ-CD) was studied by X-ray diffraction, differential scanning calorimetry (DSC), FTIR and 1 H NMR...
Inclusion complexes (ICs) formed with cyclodextrins (CDs) and polymers have been an interesting topic over the past decade. Recently, more focus has been shifted to the ICs with biodegradable polymers or copolymers because of their potential applications as novel biomaterials. This work reports the IC formation between CDs and biodegradable poly(ε-caprolactone)-poly(tetrahydrofuran)-poly(ε-caprolactone)...
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