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We develop a theoretical model describing the effect of applied force on the rate of enzymatic dissociation of disulfide bonds (Wiita, A. P. et al., Nature 450:124–127, 2007). The timescale characterizing the extension of the 8-domain protein chain, in which every domain contains a disulfide bond, exhibits anomalous force dependence: The extension time first increases and then decreases with increasing...
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