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Cu‐based catalysts, which are regarded as the most promising catalysts for CO2 conversion, suffer dramatic deactivation at high temperatures. In this work, LaFeO3, a typical perovskite‐type oxide, is employed to disperse and stabilize Cu particles for the reverse water gas shift reaction. Compared to traditional Cu‐based catalysts, Cu/LaFeO3 exhibits a higher conversion with 100% CO selectivity and...