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Warum Wasser und bestimmte Salze metallorganische Reagentien zerstören, wird von G. N. Khairallah, G. da Silva und R. A. J. O'Hair in ihrer Zuschrift auf S. 11159 ff. erklärt. Die Zugabe eines einzelnen Salzmoleküls zu einem metallorganischen Reagens erhöht dessen Reaktivität gegenüber Wasser deutlich. Das zweite Metallzentrum beeinflusst aktiv die grundlegenden chemischen Prozesse, die stattfinden,...
A combination of gas‐phase ion–molecule reaction experiments and theoretical kinetic modeling is used to examine how a salt can influence the kinetic basicity of organometallates reacting with water. [HCCLiCl]− reacts with water more rapidly than [HCCMgCl2]−, consistent with the higher reactivity of organolithium versus organomagnesium reagents. Addition of LiCl to [HCCLiCl]− or [HCCMgCl2]− enhances...
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