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Two configurations of molecularly imprinted bis‐aniline‐bridged Au nanoparticles (NPs) for the specific binding of the electron acceptor N,N′‐dimethyl‐4,4′‐bipyridinium (MV2+) and for the photosensitizer Zn(II)‐protoporphyrin IX (Zn(II)‐PP‐IX) are assembled on electrodes, and the photoelectrochemical features of the two configurations are discussed. Configuration I includes the MV2+‐imprinted Au NPs...
Layered metal nanoparticle structures have been shown to have application across a broad range of fields, notably as a specific and sensitive imprinting matrix for sensing targets, as a substrate for electrochemical reactions, and as a surface with which to control the uptake and release of molecules. On page 51 I. Willner and co‐workers review how the synthesis of layered nanoparticles on an electrode...
Layered metal nanoparticle (NP) assemblies provide highly porous and conductive composites of unique electrical and optical (plasmonic) properties. Two methods to construct layered metal NP matrices are described, and these include the layer‐by‐layer deposition of NPs, or the electropolymerization of monolayer‐functionalized NPs, specifically thioaniline‐modified metal NPs. The layered NP composites...
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