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Labile nature of water clusters (H 2 O) n [n=9–20] in external electric fields is explored through their vibrational IR spectra under the M06-2X density functional prescription. Field-deformable clusters on the verge of breakdown exhibit particularly low-frequency, isolated, exotic OH stretches in the range of 2591–3021cm −1 , markedly below those for their field-free counterparts,...
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