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Zwei Selenide wohnen, ach! in diesem Stoff: Die valenzpräzise Verbindung Rb4Sn5P4Se20 (siehe Bild; Rb blau, Sn grün, P schwarz, Se rot), das erste metallische Selenophosphat, stellt eine neue Hybridstruktur aus „leitfähigen“ [Sn5Se8]‐Schichten und „isolierenden“ [P2Se6]‐Liganden dar. Es hat die höchste elektrische Leitfähigkeit aller Chalkophosphate bei einer extrem niedrigen Wärmeleitfähigkeit von...
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