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Infrared spectra of syn and anti isomers of benzaldoxime and pyridine-4-aldoxime isolated in low-temperature Ar and N 2 matrixes are reported. The syn isomeric forms of these compounds are highly predominant in the matrixes after deposition. These forms were identified on the basis of their infrared spectra. Upon UV irradiation of the matrixes, new spectra appeared and were assigned to the...
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