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Radiation damage of self-assembled monolayers (SAMs), which are prototypes of thin organic layers and highly organized biological systems, has been investigated with synchrotron radiation at variable temperature. For the prototypes alkanethiolates on polycrystalline Au(111), and alkyls on monocrystalline Si(111), we have measured X-ray photoelectron spectroscopy (XPS), X-ray absorption (XAS), and...
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