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We design a novel ABA type triblock copolymer (triBCP) by performing efficient synthetic methods of chain-growth condensation polymerization (CGCP), supplemental activator and reducing agent atom transfer radical polymerization (SARA ATRP), and styrenics-assisted atom transfer radical coupling (SA ATRC). A well-defined poly(3-(N-(octyloxy)benzyl benzamide) having a 2-bromo-2-phenylacetate effective...
Two-dimensional Raman spectroscopy has been applied to provide the information on charge carriers and thermal stability of a doped poly(3-chlorothiophene) (PCTh) film. The strong spectral intensity at 1420cm −1 shows that positive polarons are the major charge carriers in doped PCTh. On the other hand, peaks in the 2D contour maps separate the overlapped bands around 1386cm −1 , confirming...
Three series of polydiphenylsiloxane (PDPS)-containing diblock copolymers were synthesized with controlled molecular weight and composition by sequential addition of the corresponding comonomers through a living anionic polymerization. These copolymers included poly(diphenylsiloxane-b-dimethylsiloxane) (PDPS/PDMS), poly(diphenylsiloxane-b-methylphenylsiloxane) (PDPS/PMPS), and poly(diphenylsiloxane-b-methyltrifluoropropylsiloxane)...
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