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Resonance Raman spectra were measured for a series of Os, Ru, and Re dinuclear and trinuclear complexes in resonance with their low-energy metal-to-metal or intervalence transfer absorption band. The spectra typically demonstrate a series of enhanced low-wavenumber Raman bands due to metal-ligand modes along with enhancement of ν(CN) bands. The spectra also demonstrate low-wavenumber polypyridine...
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