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We sought to identify an evident enthalpic-driven transition below an entropic-driven closed-loop phase transition by studying the phase behavior in miscible binary block copolymer (BCP) blends of a polystyrene-b-poly (n-butyl methacrylate) (PS-b-PnBMA) and a deuterated polystyrene-b-poly (n-hexyl methacrylate) (dPS-b-PnHMA), using small-angle x-ray scattering (SAXS) and depolarized light scattering...
Pressure dependence of various phase transitions for the miscible block copolymer (BCP) blends was evaluated by depolarized light scattering (DPLS) and small-angle neutron scattering (SANS) measurements, in which the blends consist of a polystyrene-b-poly(n-butyl methacrylate) (PS-b-PnBMA) and a deuterated polystyrene-b-poly(n-hexyl methacrylate) (dPS-b-PnHMA). Excellent baroplasticity was observed...
We present the microdomain expansion and transition behavior of binary blends of polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA)/PS homopolymers using small-angle X-ray scattering (SAXS) analysis, where the PS molecular weight (or chain length) was varied with chain length ratios (α) of 0.3, 1, and 2 with respect to the PS block length of the PS-b-PMMA. The d-spacing and order-to-disorder transition...
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