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An unusual feature has been detected in the IR spectra of the proton disolvates L–H + –L, namely strong broadening of the absorption bands of molecular groups of the organic ligand L directly bonded with H + .
SAXS investigations have shown that proton hydratosolvates in organic solutions of strong acids HAn form nanomicelle-like associates; the dependence of the size of the ‘nanomicelle’ (35–60 Å), their degree of shape distortion and tendency towards further aggregation on HAn concentration, the nature of An – and solvent basicity are discussed.
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