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Photochemical reactions in neutral molecular clusters of benzophenone with hydrogen donors formed in a supersonic free jet expansion have been studied. It has been found that intracluster hydrogen abstraction reaction takes place to form benzophenone ketyl radical in the benzophenone—1,4-cyclohexadiene mixed cluster. On the contrary, no ketyl radical has been detected when ethanol, 2-propanol, or...
The photochemistry of acetophenone and benzaldehyde with hydrogen donors has been studied in the gas phase. The quenching rate constants of the triplet acetophenone and benzaldehyde can be well correlated with the ionization potentials of hydrogen donors. The results suggested that the charge-transfer interaction plays an important role in the gas-phase reaction as in the case of condensed phase...
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