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The bis(trifluoromethanesulfonyl)amide anion ([Tf2N]−) has frequently been used as a component of ionic liquids. To investigate the effect of this anion and alkyl substituents on the thermal properties of macrocyclic metal complexes, cobalt(III) cyclam complexes [Co(cyclam)Cl2][Tf2N] and its monoalkyl derivatives were prepared (cyclam=1,4,8,11-tetraazacyclotetradecane). The corresponding hexafluorophosphate...
A series of salts comprising cationic manganese(III)-salen complexes and the Tf 2 N anion has been prepared (salen=N,N′-bis(salicylideneaminato)ethylene, Tf 2 N=bis(trifluoromethanesulfonyl)amide) to investigate the effects of axial ligands and substituents on their thermal properties. [Mn(salen)L 2 ][Tf 2 N] (L=H 2 O, pyridine) and their 5-butoxysalen analogs...
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