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In the framework of quantum chemical approximations, namely MINDO/3, MNDO, AM1 and PM3, the thermodynamic functions characteristic of the formation of dimers of alkanols (n=8-16) are calculated both in vacuum and in water. These values are compared with those calculated from experimental Π versus A isotherms of n-dodecanol, n-tetradecanol and n-hexadecanol using a thermodynamic model that assumes...
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