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Use of the ultrahigh vacuum methods of surface science allows the preparation and study of highly characterized solid–solid interfaces for tribological investigations. One of the limiting factors in the progress of our understanding of tribology has been the inability to generate solid–solid interfaces with well-defined, reproducible, atomic scale structures and compositions. The preparation of single...
Fourier-transform infrared reflection absorption spectra (FT-IRAS) have been obtained for 1-propoxide and a set of deuterated 1-propoxides at saturation coverages on the Cu(111) surface. These stable species are formed by the reaction of 1-propanol with the preoxidized Cu(111) surface. At elevated temperatures the propoxides undergo β-hydride elimination and desorb as propanals. Temperature programmed...
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