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Tricresylphosphate (TCP) is known to serve as an excellent high temperature vapor phase lubricant with some metals such as Fe but not with others such as Ni. The surface chemistry of m-TCP has been studied on clean and phosphorous covered Ni(1 0 0) surfaces in order to understand the differences between its reactivity on Fe and Ni. Our results show that upon heating to 800 K m-TCP decomposes on...
Triresylphosphate (TCP) [(CH3-C6H4O)3P=O] is the most commonly tested vapor phase lubricant and is readily available as a mixture containing all three isomers (ortho-, meta-, and para-) of the cresyl groups. The surface chemistry of ortho-, meta-, and para-TCP on Fe foil was studied in order to examine the possible differences in decomposition mechanisms among the isomers. All three TCP isomers decomposed...
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