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A low-level zirconia coating significantly stabilizes high energy alkaline super-iron cathodes, and improves the energy storage capacity of super-iron batteries. Zirconia coating is derived from ZrCl 4 in an organic medium through the conversion of ZrCl 4 to ZrO 2 . In alkaline battery system, ZrO 2 provides an intact shield for the cathode materials and the hydroxide...
A high capacity alkaline redox storage chemistry is explored based on a novel Fe 6+ /B 2− chemistry. The alkaline anodes based on transition metal borides can deliver exceptionally high electrochemical capacity. Over 3800mAh/g discharge capacity is obtained for the commercial available vanadium diboride (VB 2 ), much higher than the theoretical capacity of commonly used zinc...
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