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(R)‐1‐phenyl‐ethanol (PhEtOH) and the different isomers of (R)‐1‐(chlorophenyl)ethanol (ClPhEtOH) exhibit very interesting electronic circular dichroism (ECD) in methanol. In all cases, the spectrum shows clear vibronic features, but it is monosignated and negative for PhEtOH and meta‐ClPhEtOH, positive for the ortho isomer and bisignated for the para isomer. We used computational chemistry to rationalise...
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